Product ID:UCAR AIRCRAFT DEICING FLUID 11-D PM-5178
MSDS Date:06/13/1989
FSC:6810
NIIN:00N017427
MSDS Number: BNNMD

UNION CARBIDE CHEMICALS & PLASTICS CO INC

39 OLD RIDGEBURY ROAD
DANBURY, CT 06817-0001
US

Emergency Phone: 800-822-4357

Info Phone: 304-744-3487

Cage: DO713

UNION CARBIDE CORP

DANBURY, CT 06817-0001 US

Telephone: 800-822-4357/732-563-5522 (MSDS)

Cage: 61637

BEFORE COMA, SEIZURE, & RENAL FAILURE HAVE OCCURED

RTECS: 9999999ZZ

DESCRIBED IN NUMBER OF PATIENTS FOLLOWING POIS

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ELUCIDATED, BUT APPEARS TO BE NONCARDIOGENIC IN

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END-EXPIRATORY PRESS MAY BE REQD. MAY BE CRANIAL

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ETHYLENE GLYCOL.IN PARTICULAR, EFTS HAVE BEEN

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PRESENTING WITH BILATERAL FACIAL PARALYSIS,

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WHERE VAPOR IS EXPECTED TO BE VENTED TO WORKPLACE.

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DIZZ & NYSTAGMUS.RPTD SKIN CONT MAY CAUSE SENSIT

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PRDCE DOSE-RELATED TERATOGENIC EFTS IN RATS/MICE WHEN

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IN STUDY W/CONC OF 150,1000 & 2500 MG/M3 FOR 6 HOURS

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EFTS WERE PRDCD AT HIGHEST CONC, BUT ONLY IN MICE. IN

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BY WHOLE-BODY/NOSE-ONLY EXPOS, IT WAS SHOWN THAT

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& DEVELOPMENTAL TOX W/MINIMAL EVIDENCE OF

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AS AN ANIMAL TERATOGEN; THERE IS CURRENTLY NO AVAIL

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DEFECTS IN HUMANS. CUTANEOUS APPLIC OF ETHYLENE

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HIGH AEROSOL CONC IS MINIMALLY EFFECTIVE IN

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DEVELOPMENTAL TOXICITY IS PERORALLY.

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MAY BLOCK FORM OF NEPHROTOXIC METABOLITES

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AS 5% SOLN IN SODIUM BICARBONATE, AT RATE OF ABOUT

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ETHANOL IN BLOOD IS 100 MG/DL. HEMODIALYSIS MAY BE

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DEHYDROGENASE, HAS BEEN USED THERAPEUTICALLY TO

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ETHYLENE GLYCOL (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 81%

OSHA PEL 50 PPM, C

ACGIH TLV: 50 PPM, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

50 PPM TOTAL, 10

CAS: 111-46-6

RTECS: ID5950000

Fraction By Weight: 10%

ADDITIVES; (NON-HAZARDOUS PROCESSING ADDITIVES)

Fraction By Weight: 9%

CORNEAL INJ IS NOT ANTICIPATED. (CHRONIC)INHAL OF

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:(ACUTE) INGEST: MAY CAUSE ABDOMINAL
DISCOMFORT/PAIN, NAUS,VOMIT,DIZZ,DROW,MALAISE, BLURRING VISION,
IRRIT, LUMBAR PAIN,OLIGURIA, UREMIA, & CNS EFTS, INCL IRREG EYE
MOVEMENTS, CONVULSIONS/COMA. CARDIAC FAILURE & PULM EDEMA MAY
DEVELOP. SEV KIDNEY DMG FOLLOWS SWALLOWING OF LRG VOL OF ETHYLENE
GLYCOL. MAY(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: BE FATAL. A FEW RPTS HAVE BEEN
PUBLISHED DESCRIBING DEVELOPMENT OF WEAK OF FACIAL
MUSCLES,DIMINISHED HEARING,& DFCLTY W/SWALLOWING, DURING LATE
STAGES OF SEV POIS. INHAL: MAY CAUSE IRRIT OF NOSE/THROAT W/HDCH,
PARTICULARLY FROM MISTS. HIGH VAP CONC MAY PRDCE NAUS, VOMIT, HDCH,
DIZZ, & IRREG EYE (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: IF CONSCIOUS, GIVE 2 GLASSES OF H*2O/INDUCE VOMIT.
CALL PHYS IMMED. SKIN: REMOVE CONTAM CLTHG & FLUSH SKIN W/H*2O.
INHAL: REMOVE TO FRESH AIR. CALL PHYS IF SYMP PERSIST. EYES: IMMED
FLUSH W/H* 2O, & CONTINUE WASHING EYES FOR SEV MINUTES. NOTES TO
PHYS: PRINCIPAL TOX EFTS OF ETHYLENE GLYCOL, WHEN SWALLOWED, ARE
KIDNEY DMG & METABOLIC ACIDOSIS. ETHANOL IS ANTIDOTAL, & ITS EARLY
ADMIN (ING 15)

Flash Point Method:COC
Flash Point:265F,129C
Lower Limits:3.2%
Upper Limits:15%
Extinguishing Media:APPLY ALCOHOL-TYPE/ALL-PURPOSE-TYPE FOAMS BY MFR
RECOM TECHNIQUES FOR LRG FIRES. USE CO*2/DRY CHEM MEDIA FOR SML
FIRES.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. SMALL
SPILLS COULD BE FLUSHED W/LRG AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT SWALLOW, BRTH MIST FROM SPRAY.
AVOID PRLNGD/RPTD BRTHG OF VAP. AVOID CONT W/EYES. KEEP CNTNR CLSD.
USE WITH ADEQUATE VENTILATION.
Other Precautions:SPRAYING-WORKERS SHD WEAR SUITABLE PROT EQUIP.
AIRCRAFT DEICING FLUID SHD NOT BE SWALLOWED, NOR SHD MIST BE BRTH.
HANDLERS SHOULD AVOID PROLONGED OR REPEATED BREATHING OF VAPOR AND
CONTACT WITH EYES, & SHOULD ALWAYS WASH THORO AFTER HNDLG.

Respiratory Protection:IF PERSONAL EXPOSURE EXCEEDS EXPOSURE LIMITS,
SELECT IN ACCORDANCE WITH 29 CFR 1910.134. NIOSH/MSHA APPROVED
RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER
RECOM.
Ventilation:GEN (MECH) ROOM VENT IS EXPECTED TO BE ADEQ IF HANDLED IN
COVERED EQUIP. LOC EXHST VENT IS NEEDED AT POINTS (ING 25)
Protective Gloves:NATRL RUB, NITRILE, NEOPRENE,PVC GLOVES.
Eye Protection:CHEM WORK GOG/FULL LGTH FACESHLD .
Other Protective Equipment:EYE BATH AND SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SPEC GRAV: @ 20C (H*2O=1). MATLS TO AVOID: STRONG OXIDIZING AGENTS &
MATLS REACTIVE W/HYDROXYL CMPDS. EFTS OF OVEREXP: MOVEMENTS. SKIN:
NO EVIDENCE OF ADVERSE EFTS FROM AVAIL INFORM. EYE: LIQ, VAP, &
MIST, MAY CAUSE DISCOMFORT IN EYE W/PERSISTENT CONJUNCT, SEEN AS
SLIGHT EXCESS REDNESS OF CONJUNCTIVA. SERIOUS (ING 4)

HCC:T6
Boiling Pt:B.P. Text:313F,156C
Melt/Freeze Pt:M.P/F.P Text:-26F,-32C
Vapor Pres:1.5 @ 20C
Vapor Density:1.9
Spec Gravity:1.116(SUP DATA)
Evaporation Rate & Reference:0.13 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:BRIGHT ORANGE LIQUID; GLYCOL ODOR.

Stability Indicator/Materials to Avoid:YES
EXPLO DECOMP MAY OCCUR IF COMBINED W/STRONG ACIDS/STRONG BASES &
SUBJECTED TO ELEVATED TEMPS. AVOID CONTAM W/(SUPP DATA)
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:BURNING CAN PRODUCE CO AND/OR CO*2.

Waste Disposal Methods:INCINERATE IN FURNACE, WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATIONS. AT VERY LOW
CONCENTRATIONS IN WATER, IT SHOULD BE POSS TO DISP OF MATL IN
BIOLOGICAL WASTEWATER TREATMEN T PLANT.

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